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"Electrons added to atomic orbitals of the same energy will remain unpaired with parallel spins until the subshell is more than half-filled" is a statement of


A) the aufbau principle.
B) Hund's rule.
C) the Pauli exclusion principle.
D) the periodic law.
E) the singularity rule.

F) A) and E)
G) All of the above

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Select the most acidic compound from the following:


A) SO2
B) Al2O3
C) CaO
D) PbO
E) H2O

F) A) and C)
G) B) and E)

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A negative electron affinity implies that the atom repels an approaching electron.

A) True
B) False

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State Hund's rule, and show how it applies to the ground state of phosphorus atoms.

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Electrons occupy orbitals within the sam...

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What is the correct order of decreasing size of the following ions?


A) P > Cl¯ > K+ > Ca2+
B) Ca2+ > K+ > Cl¯ > P
C) K+ > Cl¯ > Ca2+ > P
D) K+ > Cl¯ > P > Ca2+
E) None of these choices is correct.

F) A) and D)
G) A) and E)

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In Mendeleev's version of the periodic table, the elements were arranged in order of increasing atomic number.

A) True
B) False

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The difference in energies between the 1s and 2s orbitals is due to the penetration effect.

A) True
B) False

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Electron affinities of neutral atoms may be positive or negative.

A) True
B) False

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Which of the following elements has the smallest first ionization energy?


A) Rb
B) Mg
C) I
D) As
E) F

F) B) and E)
G) None of the above

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. Also, explain why the values of these properties are so different between these two groups.

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Group 1A (1) atoms are much la...

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Energy states of atoms containing more than one electron arise from nucleus-electron and electron-electron interactions. Which of the following statements correctly describes these effects?


A) Larger nuclear charge lowers energy, more electrons in an orbital lowers energy.
B) Larger nuclear charge lowers energy, more electrons in an orbital increases energy.
C) Smaller nuclear charge lowers energy, more electrons in an orbital lowers energy.
D) Smaller nuclear charge lowers energy, more electrons in an orbital increases energy.
E) None of these statements is generally correct.

F) B) and E)
G) All of the above

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Which of the following electron configurations is correct for the excited state of an element?


A) [He]2s22p5
B) [Ne]3s23p1
C) [Ar]4s14p1
D) [Kr]5s24d7
E) [He]1p1

F) B) and D)
G) B) and C)

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Moseley's measurements of nuclear charges of the elements provided the basis for arranging the elements of the periodic table in order of increasing atomic number.

A) True
B) False

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The electronic structure 1s22s22p63s23p64s23d8 refers to the ground state of:


A) Kr
B) Ni
C) Fe
D) Pd
E) None of these choices is correct.

F) B) and C)
G) C) and E)

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In the electron configuration [Ar]4s23d104p4, which are valence electrons?


A) all of the electrons after the [Ar]
B) only the 4s2 electrons
C) only the 3d10 electrons
D) only the 4p4 electrons
E) both the 4s2 and the 4p4 electrons

F) A) and E)
G) None of the above

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According to the exclusion principle, two is the maximum number of electrons in an atom which can share the same four quantum numbers.

A) True
B) False

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First ionization energies of neutral atoms may be positive or negative.

A) True
B) False

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Select the element with the greatest metallic character.


A) Li
B) Ca
C) Al
D) Pb
E) Cs

F) B) and E)
G) None of the above

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Select the correct electron configuration for Te (Z = 52) .


A) [Kr]5s25p64d8
B) [Kr]5s25d105p4
C) [Kr]5s24d105p6
D) [Kr]5s24f14
E) [Kr]5s24d105p4

F) B) and C)
G) A) and B)

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Select the correct set of quantum numbers (n, l, ml, ms) for the first electron removed in the formation of a cation for strontium, Sr.


A) 5, 1 , 0, -½
B) 5, 1, 0, ½
C) 5, 0, 1, ½
D) 5, 1, 1, ½
E) 5, 0, 0, -½

F) B) and E)
G) A) and C)

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