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In combustion analysis, the oxygen content of a substance is equal to the total oxygen in the CO2 and H2O collected in the absorbers.

A) True
B) False

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The number of hydrogen atoms in 0.050 mol of C3H8O3 is


A) 3.0 × 10 22 H atoms.
B) 1.2 × 10 23 H atoms.
C) 2.4 × 10 23 H atoms.
D) 4.8 × 10 23 H atoms.
E) None of these choices are correct.

F) A) and C)
G) D) and E)

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Tetraphosphorus hexaoxide ( ℳ = 219.9 g/mol) is formed by the reaction of phosphorus with oxygen gas. P4(s) + 3O2(g) → P4O6(s) If a mixture of 75.3 g of phosphorus and 38.7 g of oxygen produce 43.3 g of P4O6, what is the percent yield for the reaction?


A) 57.5%
B) 48.8%
C) 38.0%
D) 32.4%
E) 16.3%

F) B) and D)
G) D) and E)

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Calculate the number of oxygen atoms in 29.34 g of sodium sulfate, Na2SO4.


A) 1.244 × 10 23 O atoms
B) 4.976 × 10 23 O atoms
C) 2.409 × 10 24 O atoms
D) 2.915 × 10 24 O atoms
E) 1.166 × 10 25 O atoms

F) All of the above
G) D) and E)

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Aluminum oxide, Al2O3, is used as a filler for paints and varnishes as well as in the manufacture of electrical insulators. Calculate the number of moles in 47.51 g of Al2O3.


A) 2.377 mol
B) 2.146 mol
C) 1.105 mol
D) 0.4660 mol
E) 0.4207 mol

F) A) and D)
G) A) and E)

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D

Magnesium reacts with iron(III) chloride to form magnesium chloride (which can be used in fireproofing wood and in disinfectants) and iron. 3Mg(s) + 2FeCl3(s) → 3MgCl2(s) + 2Fe(s) A mixture of 41.0 g of magnesium (ℳ = 24.31 g/mol) and 175 g of iron(III) chloride (ℳ = 162.2 g/mol) is allowed to react. What mass of magnesium chloride (ℳ = 95.21 g/mol) is formed?


A) 68.5 g MgCl 2
B) 77.0 g MgCl 2
C) 71.4 g MgCl 2
D) 107 g MgCl 2
E) 154 g MgCl 2

F) B) and D)
G) A) and E)

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The iodine "clock reaction" involves the following sequence of reactions occurring in a reaction mixture in a single beaker. IO3(aq) + 5I-(aq) + 6H+(aq) → 3I2(aq) + 3H2O(l) I2(aq) + 2S2O32-(aq) → 2I-(aq) + S4O62-(aq) The molecular iodine (I2) formed in reaction 1 is immediately used up in reaction 2, so that no iodine accumulates. In one experiment, a student made up a reaction mixture which initially contained 0.0020 mol of iodate ions (IO3) . If the iodate ions reacted completely, how many moles of thiosulfate ions (S2O32) were needed in reaction 2, in order to react completely with the iodine (I2) produced in reaction 1?


A) 0.0020 mol
B) 0.012 mol
C) 0.0040 mol
D) 0.0010 mol
E) 0.0060 mol

F) A) and C)
G) C) and D)

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Potassium dichromate, K2Cr2O7, is used in tanning leather, decorating porcelain, and water proofing fabrics. Calculate the number of chromium atoms in 78.82 g of K2Cr2O7.


A) 9.490 × 10 25 Cr atoms
B) 2.248 × 10 24 Cr atoms
C) 1.124 × 10 24 Cr atoms
D) 3.227 × 10 23 Cr atoms
E) 1.613 × 10 23 Cr atoms

F) C) and E)
G) A) and B)

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Calculate the molar mass of tetraphosphorus decaoxide, P4O10, a corrosive substance which can be used as a drying agent.


A) 469.73 g/mol
B) 283.89 g/mol
C) 190.97 g/mol
D) 139.88 g/mol
E) 94.97 g/mol

F) A) and D)
G) C) and E)

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Calculate the molar mass of rubidium carbonate, Rb2CO3.


A) 340.43 g/mol
B) 255.00 g/mol
C) 230.94 g/mol
D) 145.47 g/mol
E) 113.48 g/mol

F) A) and B)
G) A) and C)

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A normal breath takes in about 1.0 L of air. Assuming that air has an average molar mass of 28.8 g, and that its density is 0.97 g/L, how many molecules of air do you take in with each breath?


A) 2.0 × 10 22
B) 2.2 × 10 22
C) 5.8 × 10 23
D) 1.7 × 10 25
E) 1.8 × 10 25

F) B) and D)
G) None of the above

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How many atoms are in a drop of mercury that has a diameter of 1.0 mm? (Volume of a sphere is 4πr3/3; density of mercury = 13.6 g/cm3)


A) 2.1 × 10 19
B) 1.7 × 10 20
C) 2.1 × 10 22
D) 1.7 × 10 23
E) None of these choices are correct.

F) A) and E)
G) A) and C)

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Hydroxylamine hydrochloride is a powerful reducing agent which is used as a polymerization catalyst. It contains 5.80 mass % H, 20.16 mass % N, 23.02 mass % O, and 51.02 mass % Cl. What is its empirical formula?


A) H 2N 7O 8Cl 18
B) H 2N 2O 2Cl
C) HN 3O 4C l9
D) H 4NOCl
E) H 4NOCl 2

F) A) and E)
G) C) and D)

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Balance the following equation: Ca3(PO4) 2(s) + SiO2(s) + C(s) → CaSiO3(s) + CO(g) + P4(s)


A) Ca 3(PO 4) 2( s) + 3SiO 2( s) + 8C( s) → 3CaSiO 3( s) + 8CO( g) + P4( s)
B) Ca 3(PO 4) 2( s) + 3SiO 2( s) + 14C(s) → 3CaSiO 3( s) + 14CO( g) + P 4( s)
C) Ca 3(PO 4) 2( s) + 3SiO 2( s) + 8C( s) → 3CaSiO 3( s) + 8CO( g) + 2P 4( s)
D) 2Ca 3(PO 4) 2( s) + 6SiO 2( s) + 10C( s) → 6CaSiO 3( s) + 10CO( g) + P 4( s)
E) 2Ca 3(PO 4) 2( s) + 6SiO 2( s) + 10C( s) → 6CaSiO 3( s) + 10CO( g) + 4P 4( s)

F) D) and E)
G) A) and C)

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Balance the following equation: B2O3(s) + HF(l) → BF3(g) + H2O(l)


A) B 2O 3( s) + 6HF( l) → 2BF 3( g) + 3H 2O( l)
B) B 2O 3( s) + H 6F 6( l) → B 2F 6( g) + H 6O 3( l)
C) B 2O 3( s) + 2HF( l) → 2BF 3( g) + H 2O( l)
D) B 2O 3( s) + 3HF( l) → 2BF 3( g) + 3H 2O( l)
E) B 2O 3( s) + 6HF( l) → 2BF 3( g) + 6H 2O( l)

F) A) and E)
G) A) and D)

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Calculate the mass in grams of 8.35 × 1022 molecules of CBr4.


A) 0.0217 g
B) 0.139 g
C) 7.21 g
D) 12.7 g
E) 46.0 g

F) None of the above
G) A) and B)

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Terephthalic acid, used in the production of polyester fibers and films, is composed of carbon, hydrogen, and oxygen. When 0.6943 g of terephthalic acid was subjected to combustion analysis it produced 1.471 g CO2 and 0.226 g H2O. What is its empirical formula?


A) C 2H 3O 4
B) C 3H 4O 2
C) C 4H 3O 2
D) C 5H 12O 4
E) C 2H 2O

F) A) and E)
G) B) and D)

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Ammonia, an important source of fixed nitrogen that can be metabolized by plants, is produced using the Haber process in which nitrogen and hydrogen combine. N2(g) + 3H2(g) → 2NH3(g) How many grams of nitrogen are needed to produce 325 grams of ammonia?


A) 1070 g
B) 535 g
C) 267 g
D) 178 g
E) 108 g

F) A) and B)
G) B) and D)

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The iodine "clock reaction" involves the following sequence of reactions occurring in a reaction mixture in a single beaker. 1.IO3(aq) + 5I(aq) + 6H+(aq) → 3I2(aq) + 3H2O(l) 2.I2(aq) + 2S2O32(aq) → 2I(aq) + S4O62aq) The molecular iodine (I2) formed in reaction 1 is immediately used up in reaction 2, so that no iodine accumulates. What is the overall reaction occurring in this experiment?


A) IO 3 ( aq) + 3I ( aq) + 2S 2O3 2 aq) + 6H+( aq) → 2I 2( aq) + S 4O6 2 ( aq) + 3H 2O( l)
B) IO 3( aq) + 4S 2O3 2 ( aq) + 6H+( aq) → I ( aq) + 2S 4O6 2 ( aq) + 3H 2O( l)
C) IO 3 aq) + 6S 2O3 2 aq) + 6H+( aq) → I -( aq) + 3S 4O6 2 aq) + 3H 2O( l)
D) IO3 ( aq) + I2( aq) + 8S2O32 ( aq) + 6H+( aq) → 3I-( aq) + 4S4O62 ( aq) + 3H2O( l)
E) IO3( aq) + 2I2( aq) + 6S2O32 (aq) + 6H+( aq) → 5I -( aq) + 3S4O62−( aq) + 3H2O( l)

F) B) and C)
G) A) and E)

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C

An important reaction sequence in the industrial production of nitric acid is the following: N2(g) + 3H2(g) → 2NH3(g) 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l) Starting from 20.0 mol of nitrogen gas in the first reaction, how many moles of oxygen gas are required in the second one?


A) 12.5 mol O 2
B) 20.0 mol O 2
C) 25.0 mol O 2
D) 50.0 mol O 2
E) 100. mol O 2

F) A) and E)
G) None of the above

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D

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