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What is the mass % of K2SO4 in an aqueous solution that has a mole fraction of K2SO4, X = 0.350


A) 80.9%
B) 83.9%
C) 85.9%
D) 87.9%
E) None of the above

F) A) and B)
G) A) and D)

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A 23.0% by mass LiCl solution is prepared in water. What is the mole fraction of the water


A) 0.113
B) 0.127
C) 0.873
D) 0.887
E) 0.911

F) A) and B)
G) A) and C)

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The vapor pressure of a solution depends on the chemical nature of the solvent.

A) True
B) False

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At 10 \circ C one volume of water dissolves 3.10 volumes of chlorine gas at 1.00 atm pressure. What is the Henry's Law constant in mol/L·atm


A) 0.043
B) 0.13
C) 3.1
D) 3.8
E) 36

F) D) and E)
G) A) and C)

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What is the freezing point of a solution prepared from 50.0 g ethylene glycol (C2H6O2) and 85.0 g H2O Kf of water is 1.86 \circ C/m.


A) 17.6 \circ C
B) 1.50 \circ C
C) -1.50 \circ C
D) -17.6 \circ C
E) -176 \circ C

F) A) and E)
G) B) and C)

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A solution of chloroform, CHCl3, and acetone, (CH3) 2CO, exhibits a negative deviation from Raoult's law. This result implies that


A) chloroform-chloroform interactions are stronger than chloroform-acetone interactions.
B) chloroform-chloroform interactions are weaker than chloroform-acetone interactions.
C) acetone-acetone interactions are stronger than chloroform-acetone interactions.
D) acetone-acetone interactions are weaker than chloroform-acetone interactions.
E) Both B and D.
F) Both A and C.

G) E) and F)
H) A) and B)

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The osmotic pressure of a 0.010 M MgSO4 solution at 25 \circ C is 0.318 atm. Calculate i, the van't Hoff factor, for this MgSO4 solution.


A) 0.013
B) 1.3
C) 1.5
D) 2.0
E) 76.8

F) All of the above
G) B) and E)

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In how many grams of water should 25.31 g of potassium nitrate (KNO3) be dissolved to prepare a 0.1982 m solution


A) 250.0 g
B) 792.0 g
C) 1000. g
D) 1,263 g
E) 7,917 g

F) C) and D)
G) None of the above

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Using your knowledge of osmosis or osmotic pressure decide if the following statement is true or false: -Drinking salt water actually dehydrates our tissues.

A) True
B) False

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How many liters of ethylene glycol antifreeze (C2H6O2) would you add to your car radiator containing 15.0 L of water if you needed to protect your engine to -17.8 \circ C (The density of ethylene glycol is 1.1 g/mL. For water, Kf = 1.86 \circ C/m.)


A) 6.1 L
B) 7.1 L
C) 8.1 L
D) 9.1 L
E) None of the above

F) A) and B)
G) All of the above

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C

What is the boiling point of a solution of 12.0 g of urea (CH4N2O) in 165.0 g of water (Kb (H2O) = 0.52 \circ C/m)


A) 99.4 \circ C
B) 100.0 \circ C
C) 100.6 \circ C
D) 106.2 \circ C
E) 108.4 \circ C

F) B) and E)
G) None of the above

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Which of the following concentration units will change with temperature


A) Percent mass
B) Mole fraction
C) Molality
D) Molarity
E) None of the above will change with temperature

F) A) and C)
G) C) and D)

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D

A 100. mL sample of water is taken from the Great Salt Lake, and the water is allowed to evaporate. The salts that remain (mostly NaCl) have a mass of 31.9 g Calculate the original concentration of NaCl, in g per liter, in each water sample.


A) 349 g/L
B) 339 g/L
C) 329 g/L
D) 319 g/L
E) None of the above

F) A) and C)
G) D) and E)

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Plasma is the fluid portion of blood. The concentration of acetylsalicylic acid (aspirin, C9H8O4, molar mass = 180. g/mol) in your plasma is found to be 2.99 * 10-4 M after you take two tablets of aspirin. If the volume of your plasma is 5.85 L, what is the molality, m, of aspirin in your blood (Assume density of plasma is 1.00 g/mL.)


A) 4.99 * 10-4 m
B) 3.99 * 10-4 m
C) 2.99 * 10-4 m
D) 1.99 * 10-4 m
E) None of the above

F) B) and E)
G) C) and D)

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Pure benzene, C6H6, freezes at 5.5 \circ C and boils at 80.1 \circ C. What is the boiling point of a solution consisting of cyclohexane (C6H12) dissolved in benzene if the freezing point of this solution is 0.0 \circ C (For benzene, Kf = 5.12 \circ C/m, Kb = 2.53 \circ C/m; for cyclohexane, Kf = 20.0 \circ C/m, Kb = 2.79 \circ C/m)


A) 77.4 \circ C
B) 80.9 \circ C
C) 82.8 \circ C
D) 83.1 \circ C
E) 91.2 \circ C

F) B) and C)
G) A) and B)

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How many grams of sucrose (C12H22O11, 342.3 g/mol) would be needed to make 2.5 L of a solution with an osmotic pressure of 14 atm at 25 \circ C (R = 0.0821 L·atm/K·mol)


A) 0.57 g
B) 6.8 g
C) 2.0 * 102 g
D) 4.9 * 102 g
E) 5.8 * 103 g

F) D) and E)
G) A) and E)

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D

Calculate the freezing point of a solution made from 22.0 g of octane (C8H18) dissolved in 148.0 g of benzene. Benzene freezes at 5.50 \circ C and its Kf value is 5.12 \circ C/m.


A) -1.16 \circ C
B) 0.98 \circ C
C) 5.49 \circ C
D) 6.66 \circ C
E) 12.2 \circ C

F) A) and B)
G) A) and C)

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What is the osmotic pressure of a solution that contains 13.7 g of propyl alcohol (C3H7OH) dissolved in enough water to make 500. mL of solution at 27 \circ C


A) 0.0100 atm
B) 0.0140 atm
C) 0.0370 atm
D) 0.456 atm
E) 11.2 atm

F) A) and B)
G) B) and D)

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Which of the following liquids would make a good solvent for iodine, I2


A) HCl
B) H2O
C) CH3OH
D) NH3
E) CS2

F) A) and D)
G) C) and D)

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What is the mole fraction of sodium phosphate in a 0.142 M Na3PO4(aq) solution that has a density of 1.015 g/mL


A) 0.00157
B) 0.00257
C) 0.00357
D) 0.00457
E) None of the above

F) A) and B)
G) A) and C)

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