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Heats of solution may be either positive or negative.

A) True
B) False

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Colloidal particles may be either solids, liquids, or gases.

A) True
B) False

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Safrole is used as a topical antiseptic. Calculate the vapor pressure of a solution prepared by dissolving 0.75 mol of safrole in 950 g of ethanol ( Safrole is used as a topical antiseptic. Calculate the vapor pressure of a solution prepared by dissolving 0.75 mol of safrole in 950 g of ethanol (   = 46.07 g/mol) . P°<sub>ethanol</sub> = 50.0 torr at 25°C. A)  1.8 torr B)  11 torr C)  15 torr D)  40 torr E)  48 torr = 46.07 g/mol) . P°ethanol = 50.0 torr at 25°C.


A) 1.8 torr
B) 11 torr
C) 15 torr
D) 40 torr
E) 48 torr

F) B) and E)
G) A) and D)

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Calcium nitrite is used as a corrosion inhibitor in lubricants. What is the molality of a solution prepared by dissolving 18.5 g of calcium nitrite in 83.5 g of distilled water?


A) 0.0342 m
B) 0.0855 m
C) 0.222 m
D) 0.444 m
E) 1.68 m

F) C) and D)
G) B) and D)

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The backbone of a protein chain consists of carbon, nitrogen, and oxygen atoms.

A) True
B) False

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Cadmium bromide is used in photography and lithography. Calculate the molality of a solution prepared by dissolving 45.38 g of CdBr2 in 375.0 g of water.


A) 0.03035 m
B) 0.01600 m
C) 0.1210 m
D) 0.4446 m
E) none of the above

F) A) and D)
G) All of the above

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The concentration of iodine in sea water is 60. parts per billion by mass. If one assumes that the iodine exists in the form of iodide anions, what is the molarity of iodide in sea water? (The density of sea water is 1.025 g/mL.)


A) 4.8 × 10-13 M
B) 4.8 × 10-10 M
C) 4.8 × 10-7 M
D) 4.7 × 10-4 M
E) 4.7 × 10-1 M

F) A) and E)
G) A) and C)

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Select the weakest electrolyte from the following set.


A) Na2SO4
B) KCl
C) CH3CH2COOH, propionic acid
D) CaCl2
E) LiOH

F) D) and E)
G) B) and E)

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Based only on the relative lattice energies of the compounds below, which one would be expected to have the lowest solubility in water?


A) NaBr
B) CaS
C) NaOH
D) KI
E) CsCl

F) B) and C)
G) D) and E)

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If a 100-mL sample of a volatile liquid such as diethyl ether is introduced into a 250-mL flask which is immediately sealed, the pressure inside will increase above atmospheric pressure. Explain.

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The pressure inside the flask will initi...

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The density of pure water at 25°C is 0.997 g/mL. Considering water as being both solvent and solute, calculate its molarity.

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Methane has a Henry's Law constant (k) of 9.88 × 10-2 mol/(L·atm) when dissolved in benzene at 25°C. How many grams of CH4 will dissolve in 3.00 L of benzene if the partial pressure of CH4 is 1.48 atm?


A) 0.0667 g
B) 0.146 g
C) 2.34 g
D) 4.83 g
E) 7.02 g

F) B) and E)
G) C) and E)

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Dimethylglyoxime, DMG, is an organic compound used to test for aqueous nickel(II) ions. A solution prepared by dissolving 65.0 g of DMG in 375 g of ethanol boils at 80.3°C. What is the molar mass of DMG? Kb = 1.22°C/m, boiling point of pure ethanol = 78.5°C


A) 44.1 g/mol
B) 65.8 g/mol
C) 117 g/mol
D) 131.6 g/mol
E) 553 g/mol

F) D) and E)
G) C) and D)

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Sodium hydroxide is a common ingredient in drain cleaners such as Drano. The mole fraction of sodium hydroxide in a saturated aqueous solution is 0.310. What is the molality of the solution?


A) 0.310 m
B) 0.690 m
C) 1.24 m
D) 12.4 m
E) 25.0 m

F) A) and B)
G) C) and D)

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Which of the following aqueous liquids will have the lowest freezing point?


A) 0.5 m C12H22O11 (sucrose)
B) 0.5 m Ca(NO3) 2
C) 0.5 m NiSO4
D) 0.5 m Li3PO4
E) pure water

F) A) and D)
G) All of the above

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Helical segments of protein molecules arise through hydrogen bonding between C=O and N-H groups.

A) True
B) False

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Which, if any, of the following features is common to soaps, detergents, phospholipids, and channel-forming antibiotics?


A) They all contain fatty acids.
B) They all contain phosphate groups.
C) They all contain polypeptide chains.
D) Their function depends on the dual polarity of their molecules.
E) They have none of the above features in common.

F) C) and E)
G) A) and C)

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Raoult's Law relates the vapor pressure of a solvent above a solution to the mole fraction of the solvent and the vapor pressure of the pure solvent.

A) True
B) False

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Which of the following statements describes the correct method of preparation of 1.00 L of a 2.0 M urea solution? Which of the following statements describes the correct method of preparation of 1.00 L of a 2.0 M urea solution?   <sub>urea</sub> = 60.06 g/mol A)  Dissolve 120 g of urea in 1.00 kg of distilled water. B)  Dissolve 120 g of urea in 880 g of distilled water. C)  Dissolve 120 g of urea in enough distilled water to produce 1.00 L of solution. D)  Dissolve 120 g of urea in 1.00 liter of distilled water. E)  The density of urea is needed in order to do this calculation. urea = 60.06 g/mol


A) Dissolve 120 g of urea in 1.00 kg of distilled water.
B) Dissolve 120 g of urea in 880 g of distilled water.
C) Dissolve 120 g of urea in enough distilled water to produce 1.00 L of solution.
D) Dissolve 120 g of urea in 1.00 liter of distilled water.
E) The density of urea is needed in order to do this calculation.

F) A) and D)
G) A) and C)

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Two aqueous solutions are prepared: 2.0 m Cu(NO3) 2 and 2.0 m NaBr. Which of the following statements is true?


A) The Cu(NO3) 2 solution has a higher vapor pressure and lower freezing point than the NaBr solution.
B) The Cu(NO3) 2 solution has a higher vapor pressure and higher freezing point than the NaBr solution.
C) The Cu(NO3) 2 solution has a lower vapor pressure and lower freezing point than the NaBr solution.
D) The Cu(NO3) 2 solution has a lower vapor pressure and higher freezing point than the NaBr solution.
E) None of the above statements is true.

F) B) and C)
G) B) and D)

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